Skip to main content
All CollectionsShipping SupportShipping Guidelines
Essential Guide to the Nine Classes of Dangerous Goods
Essential Guide to the Nine Classes of Dangerous Goods
Updated over a week ago

If you want to ship your chemical goods to a country, you need to classify them based on the dangerous goods classification according to the region's laws. Therefore, Luwjistik provides you with the category of hazardous goods for each class.

You will learn the following:

What are Dangerous Goods?

We often don't think about it, but some everyday items we use can harm aircraft. For example, things like lithium batteries, dry ice, and aerosol whipped cream, which seem harmless, can become hazardous when transported by air. Factors like vibrations, static electricity, temperature changes, and pressure variations can make these items leak, release toxic fumes, start fires, or even explode if not handled properly, as stated in the update.

Following the update by IATA, Dangerous goods (also referred to as hazardous materials or hazmat) encompass articles or substances that have the potential to present risks to health, safety, property, or the environment. These materials are detailed in the roster of dangerous goods within the IATA Dangerous Goods Regulations or are categorised as per the provisions of those Regulations.

Regulatory guidelines include detailed systems for categorising hazards, helping create a structured way to understand dangerous substances. These substances are grouped into nine different categories based on the kind of risks they pose.

The Classification of Dangerous Goods

Here's a list of the nine dangerous goods classifications for your reference.

Class 1: Explosive

For Explosive class, an explosive is defined as any substance or article, including a device, intended to operate through explosive means (i.e., a rapid release of gas and heat) or capable of functioning similarly through self-contained chemical reactions, even if not explicitly designed for explosion, unless otherwise categorised under the provisions of this subchapter. This definition encompasses pyrotechnic substances or articles unless they fall under other classifications within this subchapter.

As explained in the update, there are six divisions of explosives, each associated with the behaviour of the product upon initiation, such as:

  • Division 1.1: Substances and articles with a potential for mass explosion.

  • Division 1.2: Substances and articles posing a risk of projection but lacking a mass explosion hazard.

  • Division 1.3: Substances and articles presenting a fire hazard, a minor blast or projection risk, or both.

  • Division 1.4: Substances and articles with no significant hazard, only a small risk in case of ignition during transport, with effects primarily contained within the packaging.

  • Division 1.5: Highly insensitive substances with the potential for mass explosion.

  • Division 1.6: Extremely insensitive articles with no mass explosion hazard.

Common Examples of Class 1 Explosives

  • Ammunition

  • Fireworks

  • Flares

  • Blasting caps and detonators

  • Fuse

  • Primers

  • Explosive charges such as those used for blasting, demolition, etc.

  • Detonating cord

  • Air bag inflators

  • Igniters

  • Rockets

  • TNT

  • RDX

  • PETN

Class 2: Gases

Gases class is characterised following hazardous materials regulations as substances with a vapour pressure equal to or exceeding 300 kPa at 50°C or as substances entirely in a gaseous state at 20°C under standard atmospheric pressure. This classification encompasses compressed gases, liquefied gases, dissolved gases, refrigerated liquefied gases, mixtures of gases and vapours from other classes, items containing gases, and aerosols.

There are three divisions of gases that are mentioned in the update, each associated with the behaviour of the product upon initiation, such as:

  • Division 2.1: Flammable gases.

  • Division 2.2: Non-flammable, non-toxic gases.

  • Division 2.3: Toxic gases.

Common Examples of Class 2 Gases

  • Aerosols

  • Compressed air

  • Hydrocarbon gas-powered devices

  • Fire extinguishers

  • Gas cartridges

  • Fertiliser ammoniating solution

  • Insecticide gases

  • Refrigerant gases

  • Lighters

  • Acetylene / Oxy Acetylene

  • Carbon dioxide

  • Helium / helium compounds

  • Hydrogen / hydrogen compounds

  • Oxygen / oxygen compounds

  • Nitrogen / nitrogen compounds

  • Natural gas

  • Oil gas

  • Petroleum gases

  • Butane

  • Propane

  • Ethane

  • Methane

  • Dimethyl ether

  • Propene / propylene

  • Ethylene

Class 3: Flammable Liquids

Flammable liquids, as per hazardous materials regulations, are characterised as substances that, under specified conditions, emit a combustible vapour (possess a flash point) at temperatures no higher than 60-65°C. These substances encompass liquids, liquid mixtures, or suspended or dissolved solids.

Moreover, they contain liquids presented for transportation at temperatures equal to or exceeding their flash point and materials transported in a liquid state at elevated temperatures, which release a flammable vapour at or below the highest allowable transport temperature. As shown in the update, there are no subdivisions within this class.

Common Examples of Class 3 Flammable Liquids

  • Acetone

  • Paints, lacquers and varnishes

  • Alcohols

  • Perfumery products

  • Gasoline / Petrol

  • Diesel fuel

  • Aviation fuel

  • Liquid biofuels

  • Coal tar

  • Petroleum crude oil

  • Adhesives

  • Gas oil

  • Shale oil

  • Heating oil

  • Kerosene

  • Resins

  • Tars

  • Turpentine

  • Carbamate insecticides

  • Organochlorine pesticides

  • Organophosphorus pesticides

  • Copper based pesticides

  • Esters

  • Ethers

  • Ethanol

  • Benzene

  • Methanol

  • Octanes

Class 4: Flammable Solids

Flammable solids are materials that can easily catch fire or contribute to fires during transportation due to factors like friction. They can also include substances that react strongly and release heat or solid explosives that are not easily detonated.

Additionally, this category covers materials that can heat up on their own under normal transport conditions or when exposed to air, making them likely to catch fire. It also includes substances that emit flammable gases or can spontaneously catch fire when they come into contact with water.

The update further stated that there are three divisions for Class 4 dangerous goods:

  • Division 4.1: Flammable solids, self-reactive substances and solid desensitised explosives.

  • Division 4.2: Substances liable to spontaneous combustion.

  • Division 4.3: Substances that are in contact with water emit flammable gases.

Common Examples of Class 4 Flammable Solids

  • Alkali metals

  • Metal powders

  • Aluminium phosphide

  • Sodium batteries

  • Sodium cells

  • Firelighters

  • Matches

  • Calcium carbide

  • Camphor

  • Carbon

  • Activated carbon

  • Celluloid

  • Cerium

  • Copra

  • Seed cake

  • Oily cotton waste

  • Desensitised explosives

  • Oily fabrics

  • Oily fibres

  • Ferrocerium

  • Iron oxide (spent

  • Iron sponge/direct-reduced iron (spent)

  • Metaldehyde

  • Naphthalene

  • Nitrocellulose

  • Phosphorus

  • Sulphur

Class 5: Oxidising Substances and Organic Peroxides

According to hazardous materials guidelines, Oxidisers can induce or enhance combustion, typically by releasing oxygen through a redox chemical reaction.

On the other hand, organic peroxides can be considered compounds derived from hydrogen peroxide, where organic radicals replace one or both of the hydrogen atoms in the chemical structure.

There are two divisions for class 5 in the update, including:

  • Division 5.1: Oxidising substances

  • Division 5.2: Organic peroxides

Common Examples of Class 5 Oxidising Substances and Organic Peroxides

  • Chemical oxygen generators

  • Ammonium nitrate fertilisers

  • Chlorates

  • Nitrates

  • Nitrites

  • Perchlorates

  • Permanganates

  • Persulphates

  • Aluminium nitrate

  • Ammonium dichromate

  • Ammonium nitrate

  • Ammonium persulphate

  • Calcium hypochlorite

  • Calcium nitrate

  • Calcium peroxide

  • Hydrogen peroxide

  • Magnesium peroxide

  • Lead nitrate

  • Lithium hypochlorite

  • Potassium chlorate

  • Potassium nitrate

  • Potassium chlorate

  • Potassium perchlorate

  • Potassium permanganate

  • Sodium nitrate

  • Sodium persulphate

Class 6: Toxic and Infectious Substances

Toxic substances are those that have the potential to either result in fatal or severe harm or pose a threat to human health when ingested, inhaled, or in contact with the skin. Contagious materials are those that are confirmed or can be reasonably anticipated to contain disease-causing agents.

Following regulations on hazardous materials, these agents encompass microorganisms like bacteria, viruses, rickettsiae, parasites, fungi, or other substances capable of inducing illnesses in humans or animals.

As for class 6, there are two divisions mentioned in the update, such as:

  • Division 6.1: Toxic substances

  • Division 6.2: Infectious substances

Common Examples of Class 6 Toxic and Infectious Substances

  • Medical/Biomedical waste

  • Clinical waste

  • Biological cultures / samples / specimens

  • Medical cultures / samples / specimens

  • Tear gas substances

  • Motor fuel anti-knock mixture

  • Dyes

  • Carbamate pesticides

  • Alkaloids

  • Allyls

  • Acids

  • Arsenates

  • Arsenites

  • Cyanides

  • Thiols/mercaptans

  • Cresols

  • Barium compounds

  • Arsenics / arsenic compounds

  • Beryllium/ beryllium compounds

  • Lead compounds

  • Mercury compounds

  • Nicotine / nicotine compounds

  • Selenium compounds

  • Antimony

  • Ammonium metavanadate

  • Adiponitrile

  • Chloroform

  • Dichloromethane

  • Hexachlorophene

  • Phenol

  • Resorcinol

Class 7: Radioactive Material

According to hazardous materials regulations, radioactive material is classified as any substance that contains radionuclides with activity concentrations and total activities surpassing predetermined thresholds. A radionuclide has an unstable nucleus, making it susceptible to radioactive decay. This class doesn't have any divisions, as shown in the update.

Common Examples of Class 7 Radioactive Material

  • Radioactive ores

  • Medical isotopes

  • Yellowcake

  • Density gauges

  • Mixed fission products

  • Surface contaminated objects

  • Caesium radionuclides / isotopes

  • Iridium radionuclides / isotopes

  • Americium radionuclides / isotopes

  • Plutonium radionuclides / isotopes

  • Radium radionuclides / isotopes

  • Thorium radionuclides / isotopes

  • Uranium radionuclides / isotopes

  • Depleted uranium / depleted uranium products

  • Uranium hexafluoride

  • Enriched Uranium

Class 8: Corrosives

Corrosive substances exhibit a remarkable level of reactivity, leading to pronounced chemical interactions. When these substances come into contact with other materials, they initiate chemical reactions that lead to the deterioration of the latter. In cases where this interaction involves living tissue, the consequences can be severe, causing substantial injury. As shown in the update, there are no divisions within class 8.

Common Examples of Class 8 Corrosives

  • Acids/acid solutions

  • Batteries

  • Battery fluid

  • Fuel cell cartridges

  • Dyes

  • Fire extinguisher charges

  • Formaldehyde

  • Flux

  • Paints

  • Alkylphenols

  • Amines

  • Polyamines

  • Sulphides

  • Polysulphides

  • Chlorides

  • Chlorosilanes

  • Bromine

  • Cyclohexylamine

  • Phenol / carbolic acid

  • Hydrofluoric acid

  • Hydrochloric acid

  • Sulfuric acid

  • Nitric acid

  • Sludge acid

  • Hydrogen fluoride

  • Iodine

  • Morpholine

Class 9: Miscellaneous Dangerous Goods

Miscellaneous dangerous goods include substances and articles that, during transportation, pose risks or hazards that do not fall under the purview of other defined classes.

This category includes, without being exhaustive, environmentally hazardous materials, substances transported at elevated temperatures, various miscellaneous articles and substances, genetically modified organisms and micro-organisms, and, depending on the mode of transportation, magnetised materials and aviation-regulated substances. As for the divisions, the update shows that class 9 doesn't have any.

Common Examples of Class 9 Miscellaneous Dangerous Goods

  • Dry ice / cardice / solid carbon dioxide

  • Expandable polymeric beads / polystyrene beads

  • Ammonium nitrate fertilisers

  • Blue asbestos / crocidolite

  • Lithium ion batteries

  • Lithium metal batteries

  • Battery powered equipment

  • Battery powered vehicles

  • Fuel cell engines

  • Internal combustion engines

  • Vehicles

  • Magnetised material

  • Dangerous goods in apparatus

  • Dangerous goods in machinery

  • Genetically modified organisms

  • Genetically modified micro-organisms

  • Chemical kits

  • Nail Polish and Similar Chemicals

  • First aid kits

  • Life saving appliances

  • Air bag modules

  • Seatbelt pretensioners

  • Plastics moulding compound

  • Castor bean plant products

  • Polychlorinated biphenyls

  • Polychlorinated terphenyls

  • Dibromodifluoromethane

  • Benzaldehyde

Best Practices to Package Your Dangerous Goods

Packaging requirements for shipping dangerous goods can vary based on the specific type, class, and quantity of hazardous materials being transported. Often, packaging must undergo rigorous testing and certification to align with the regulations governing the safe shipment of hazardous materials via air transport.

The choice of appropriate packaging hinges on the Packing Group classification assigned to the substance, which categorises materials by their level of hazard as follows:

  • Packing Group I: Designating highly hazardous substances.

  • Packing Group II: Identifying materials with a moderate level of danger.

  • Packing Group III: Reserved for substances posing a low level of risk.

The update also adds that it is essential to adhere to the following best practices to ensure compliance and safety:

  1. Refer to segregation tables: Avoid co-packing dangerous goods that may react dangerously when in proximity to each other—cross-reference segregation tables to make informed decisions.

  2. Adhere to package closure instructions: Precisely follow the guidelines provided by the package manufacturer for sealing and securing hazardous materials. Deviating from these instructions could compromise the package's integrity and result in non-compliance.

  3. Confirm weight limits: Ensure that the total weight of your packaged materials does not exceed the tested weight limit specified by the manufacturer (usually measured in kilograms). This step is crucial for maintaining the package's structural integrity during transport. See the UN Marking example below:

Dangerous Goods Packaging Markings

Air shipments of hazardous materials typically necessitate compliance with UN-approved packaging, also known as Performance-Oriented Packaging (POP). Performance-oriented packaging is subjected to rigorous tests to withstand the shocks, loadings, and atmospheric pressure changes generally encountered during transportation.

Packages that have successfully met these testing requirements are marked with UN certification labels, indicating the specific level of testing they have undergone. The update also suggests referring to the Package ID Table below for assistance determining the appropriate packaging identification.

(Source: faa.gov)

Glossary

Density or Specific

Gravity

For single packages containing liquids, you'll find the specific gravity of a material, i.e. /Y1.5/. For packaging intended for solids or for combination packages, an "S" in uppercase will follow the gross mass, i.e., /X13/S/.

Hydraulic Pressure

Hydraulic Pressure in Kilo-Pascal (kPa) (applies to liquids). This will follow the specific gravity.

XX

Year of Manufacture

USA

Country Where Package was Manufactured

MXXX

Code for UN Certifying Agency or Manufacturer

(Source: faa.gov)

Sample UN Markings

(Source: faa.gov)

Packaging Handling Labels for Dangerous Goods

Apart from hazard labels, proficient personnel must affix handling labels as necessary. These 14 handling labels must be employed by the staff in conjunction with the relevant hazard labels:

Label Name

Interpretation

Label

Cargo Aircraft Only Label

For items that can only be transported via cargo aircraft, ensuring compliance with strict aviation safety regulations.

Limited Quantity Hazard Label for Road and Sea

Indicating that the material is suitable for transport in limited quantities on roads and by sea, emphasising responsible handling.

Limited Quantity Hazard Labels for Air

This signifies that limited quantities of the hazardous material can be transported via air, adhering to aviation standards.

Shipper / Product / Consignee

Providing vital information about the shipper, product, and consignee for clear identification and tracking.

Overpack Label

Required when multiple packages are bundled together in a single outer container, ensuring safe handling during transport.

Package Orientation Labels (Set of 2)

Guiding handlers on the proper orientation and positioning of packages to prevent damage or leakage.

Fragile Label

Signalling that the package contains delicate materials that require gentle handling to avoid breakage or spillage.

Paper Tamper Evident Seals (Label)

Indicating that tampering with the package is evident and unauthorised access can be easily identified.

Magnetized Material Label (100mm x 90mm)

Warning of magnetised materials that require special handling considerations.

Time & Temperature Sensitive Label (100mm x 100mm)

Alerting to the sensitivity of the contents to variations in time and temperature, ensuring their integrity.

Tip and Tell Indicator Label

Providing a visual indicator of mishandling or tilting during transport, allowing for immediate inspection.

Environmentally Hazardous Substance Hazard Labels (100mm x 100mm)

Signifying materials that pose an environmental hazard, demanding extra precautions.

Cryogenic Liquid Label (75mm x 105mm)

Identifying containers carrying cryogenic liquids which require specialised handling due to frigid temperatures.

Keep Away from Heat Label (74mm x 105mm)

Warning against exposure to heat sources, preventing potential reactions or damage due to elevated temperatures.

If you encounter any issues during shipment, contact our support team at [email protected] for further information and assistance.

Did this answer your question?