If you want to ship your chemical goods to a country, you need to classify them based on the dangerous goods classification according to the region's laws. Therefore, Luwjistik provides you with the category of hazardous goods for each class.
You will learn the following:
What are Dangerous Goods?
We often don't think about it, but some everyday items we use can harm aircraft. For example, things like lithium batteries, dry ice, and aerosol whipped cream, which seem harmless, can become hazardous when transported by air. Factors like vibrations, static electricity, temperature changes, and pressure variations can make these items leak, release toxic fumes, start fires, or even explode if not handled properly, as stated in the update.
Following the update by IATA, Dangerous goods (also referred to as hazardous materials or hazmat) encompass articles or substances that have the potential to present risks to health, safety, property, or the environment. These materials are detailed in the roster of dangerous goods within the IATA Dangerous Goods Regulations or are categorised as per the provisions of those Regulations.
Regulatory guidelines include detailed systems for categorising hazards, helping create a structured way to understand dangerous substances. These substances are grouped into nine different categories based on the kind of risks they pose.
The Classification of Dangerous Goods
Here's a list of the nine dangerous goods classifications for your reference.
Class 1: Explosive
For Explosive class, an explosive is defined as any substance or article, including a device, intended to operate through explosive means (i.e., a rapid release of gas and heat) or capable of functioning similarly through self-contained chemical reactions, even if not explicitly designed for explosion, unless otherwise categorised under the provisions of this subchapter. This definition encompasses pyrotechnic substances or articles unless they fall under other classifications within this subchapter.
As explained in the update, there are six divisions of explosives, each associated with the behaviour of the product upon initiation, such as:
Division 1.1: Substances and articles with a potential for mass explosion.
Division 1.2: Substances and articles posing a risk of projection but lacking a mass explosion hazard.
Division 1.3: Substances and articles presenting a fire hazard, a minor blast or projection risk, or both.
Division 1.4: Substances and articles with no significant hazard, only a small risk in case of ignition during transport, with effects primarily contained within the packaging.
Division 1.5: Highly insensitive substances with the potential for mass explosion.
Division 1.6: Extremely insensitive articles with no mass explosion hazard.
Common Examples of Class 1 Explosives
Here are the examples of Class 1 Explosives:
Ammunition
Fireworks
Flares
Blasting caps and detonators
Fuse
Primers
Explosive charges such as those used for blasting, demolition, etc.
Detonating cord
Air bag inflators
Igniters
Rockets
TNT
RDX
PETN
Class 2: Gases
Gases class is characterised following hazardous materials regulations as substances with a vapour pressure equal to or exceeding 300 kPa at 50°C or as substances entirely in a gaseous state at 20°C under standard atmospheric pressure. This classification encompasses compressed gases, liquefied gases, dissolved gases, refrigerated liquefied gases, mixtures of gases and vapours from other classes, items containing gases, and aerosols.
There are three divisions of gases that are mentioned in the update, each associated with the behaviour of the product upon initiation, such as:
Division 2.1: Flammable gases.
Division 2.2: Non-flammable, non-toxic gases.
Division 2.3: Toxic gases.
Common Examples of Class 2 Gases
Here are the examples of Class 2 Gases:
Aerosols
Compressed air
Hydrocarbon gas-powered devices
Fire extinguishers
Gas cartridges
Fertiliser ammoniating solution
Insecticide gases
Refrigerant gases
Lighters
Acetylene / Oxy Acetylene
Carbon dioxide
Helium / helium compounds
Hydrogen / hydrogen compounds
Oxygen / oxygen compounds
Nitrogen / nitrogen compounds
Natural gas
Oil gas
Petroleum gases
Butane
Propane
Ethane
Methane
Dimethyl ether
Propene / propylene
Ethylene
Class 3: Flammable Liquids
Flammable liquids, as per hazardous materials regulations, are characterised as substances that, under specified conditions, emit a combustible vapour (possess a flash point) at temperatures no higher than 60-65°C. These substances encompass liquids, liquid mixtures, or suspended or dissolved solids.
Moreover, they contain liquids presented for transportation at temperatures equal to or exceeding their flash point and materials transported in a liquid state at elevated temperatures, which release a flammable vapour at or below the highest allowable transport temperature. As shown in the update, there are no subdivisions within this class.
Common Examples of Class 3 Flammable Liquids
Here are the examples of Class 3 Flammable Liquids:
Acetone
Paints, lacquers and varnishes
Alcohols
Perfumery products
Gasoline / Petrol
Diesel fuel
Aviation fuel
Liquid biofuels
Coal tar
Petroleum crude oil
Adhesives
Gas oil
Shale oil
Heating oil
Kerosene
Resins
Tars
Turpentine
Carbamate insecticides
Organochlorine pesticides
Organophosphorus pesticides
Copper based pesticides
Esters
Ethers
Ethanol
Benzene
Methanol
Octanes
Class 4: Flammable Solids
Flammable solids are materials that can easily catch fire or contribute to fires during transportation due to factors like friction. They can also include substances that react strongly and release heat or solid explosives that are not easily detonated.
Additionally, this category covers materials that can heat up on their own under normal transport conditions or when exposed to air, making them likely to catch fire. It also includes substances that emit flammable gases or can spontaneously catch fire when they come into contact with water.
The update further stated that there are three divisions for Class 4 dangerous goods:
Division 4.1: Flammable solids, self-reactive substances and solid desensitised explosives.
Division 4.2: Substances liable to spontaneous combustion.
Division 4.3: Substances that are in contact with water emit flammable gases.
Common Examples of Class 4 Flammable Solids
Here are the examples of Class 4 Flammable Solids:
Alkali metals
Metal powders
Aluminium phosphide
Sodium batteries
Sodium cells
Firelighters
Matches
Calcium carbide
Camphor
Carbon
Activated carbon
Celluloid
Cerium
Copra
Seed cake
Oily cotton waste
Desensitised explosives
Oily fabrics
Oily fibres
Ferrocerium
Iron oxide (spent
Iron sponge/direct-reduced iron (spent)
Metaldehyde
Naphthalene
Nitrocellulose
Phosphorus
Sulphur
Class 5: Oxidising Substances and Organic Peroxides
According to hazardous materials guidelines, Oxidisers can induce or enhance combustion, typically by releasing oxygen through a redox chemical reaction.
On the other hand, organic peroxides can be considered compounds derived from hydrogen peroxide, where organic radicals replace one or both of the hydrogen atoms in the chemical structure.
There are two divisions for class 5 in the update, including:
Division 5.1: Oxidising substances
Division 5.2: Organic peroxides
Common Examples of Class 5 Oxidising Substances and Organic Peroxides
Chemical oxygen generators
Ammonium nitrate fertilisers
Chlorates
Nitrates
Nitrites
Perchlorates
Permanganates
Persulphates
Aluminium nitrate
Ammonium dichromate
Ammonium nitrate
Ammonium persulphate
Calcium hypochlorite
Calcium nitrate
Calcium peroxide
Hydrogen peroxide
Magnesium peroxide
Lead nitrate
Lithium hypochlorite
Potassium chlorate
Potassium nitrate
Potassium chlorate
Potassium perchlorate
Potassium permanganate
Sodium nitrate
Sodium persulphate
Class 6: Toxic and Infectious Substances
Toxic substances are those that have the potential to either result in fatal or severe harm or pose a threat to human health when ingested, inhaled, or in contact with the skin. Contagious materials are those that are confirmed or can be reasonably anticipated to contain disease-causing agents.
Following regulations on hazardous materials, these agents encompass microorganisms like bacteria, viruses, rickettsiae, parasites, fungi, or other substances capable of inducing illnesses in humans or animals.
As for class 6, there are two divisions mentioned in the update, such as:
Division 6.1: Toxic substances
Division 6.2: Infectious substances
Common Examples of Class 6 Toxic and Infectious Substances
Here are the examples of Class 6 Toxic and Infectious Substances:
Medical/Biomedical waste
Clinical waste
Biological cultures / samples / specimens
Medical cultures / samples / specimens
Tear gas substances
Motor fuel anti-knock mixture
Dyes
Carbamate pesticides
Alkaloids
Allyls
Acids
Arsenates
Arsenites
Cyanides
Thiols/mercaptans
Cresols
Barium compounds
Arsenics / arsenic compounds
Beryllium/ beryllium compounds
Lead compounds
Mercury compounds
Nicotine / nicotine compounds
Selenium compounds
Antimony
Ammonium metavanadate
Adiponitrile
Chloroform
Dichloromethane
Hexachlorophene
Phenol
Resorcinol
Class 7: Radioactive Material
According to hazardous materials regulations, radioactive material is classified as any substance that contains radionuclides with activity concentrations and total activities surpassing predetermined thresholds. A radionuclide has an unstable nucleus, making it susceptible to radioactive decay. This class doesn't have any divisions, as shown in the update.
Common Examples of Class 7 Radioactive Material
Here are the examples of Class 7 Radioactive Material:
Radioactive ores
Medical isotopes
Yellowcake
Density gauges
Mixed fission products
Surface contaminated objects
Caesium radionuclides / isotopes
Iridium radionuclides / isotopes
Americium radionuclides / isotopes
Plutonium radionuclides / isotopes
Radium radionuclides / isotopes
Thorium radionuclides / isotopes
Uranium radionuclides / isotopes
Depleted uranium / depleted uranium products
Uranium hexafluoride
Enriched Uranium
Class 8: Corrosives
Corrosive substances exhibit a remarkable level of reactivity, leading to pronounced chemical interactions. When these substances come into contact with other materials, they initiate chemical reactions that lead to the deterioration of the latter. In cases where this interaction involves living tissue, the consequences can be severe, causing substantial injury. As shown in the update, there are no divisions within class 8.
Common Examples of Class 8 Corrosives
Here are the examples of Class 8 Corrosives:
Acids/acid solutions
Batteries
Battery fluid
Fuel cell cartridges
Dyes
Fire extinguisher charges
Formaldehyde
Flux
Paints
Alkylphenols
Amines
Polyamines
Sulphides
Polysulphides
Chlorides
Chlorosilanes
Bromine
Cyclohexylamine
Phenol / carbolic acid
Hydrofluoric acid
Hydrochloric acid
Sulfuric acid
Nitric acid
Sludge acid
Hydrogen fluoride
Iodine
Morpholine
Class 9: Miscellaneous Dangerous Goods
Miscellaneous dangerous goods include substances and articles that, during transportation, pose risks or hazards that do not fall under the purview of other defined classes.
This category includes, without being exhaustive, environmentally hazardous materials, substances transported at elevated temperatures, various miscellaneous articles and substances, genetically modified organisms and micro-organisms, and, depending on the mode of transportation, magnetised materials and aviation-regulated substances. As for the divisions, the update shows that class 9 doesn't have any.
Common Examples of Class 9 Miscellaneous Dangerous Goods
Here are the examples of Class 9 Miscellaneous Dangerous Goods:
Dry ice / cardice / solid carbon dioxide
Expandable polymeric beads / polystyrene beads
Ammonium nitrate fertilisers
Blue asbestos / crocidolite
Lithium ion batteries
Lithium metal batteries
Battery powered equipment
Battery powered vehicles
Fuel cell engines
Internal combustion engines
Vehicles
Magnetised material
Dangerous goods in apparatus
Dangerous goods in machinery
Genetically modified organisms
Genetically modified micro-organisms
Chemical kits
Nail Polish and Similar Chemicals
First aid kits
Life saving appliances
Air bag modules
Seatbelt pretensioners
Plastics moulding compound
Castor bean plant products
Polychlorinated biphenyls
Polychlorinated terphenyls
Dibromodifluoromethane
Benzaldehyde
Best Practices to Package Your Dangerous Goods
Packaging requirements for shipping dangerous goods can vary based on the specific type, class, and quantity of hazardous materials being transported. Often, packaging must undergo rigorous testing and certification to align with the regulations governing the safe shipment of hazardous materials via air transport.
The choice of appropriate packaging hinges on the Packing Group classification assigned to the substance, which categorises materials by their level of hazard as follows:
Packing Group I: Designating highly hazardous substances.
Packing Group II: Identifying materials with a moderate level of danger.
Packing Group III: Reserved for substances posing a low level of risk.
The update also adds that it is essential to adhere to the following best practices to ensure compliance and safety:
Refer to segregation tables: Avoid co-packing dangerous goods that may react dangerously when in proximity to each other—cross-reference segregation tables to make informed decisions.
Adhere to package closure instructions: Precisely follow the guidelines provided by the package manufacturer for sealing and securing hazardous materials. Deviating from these instructions could compromise the package's integrity and result in non-compliance.
Confirm weight limits: Ensure that the total weight of your packaged materials does not exceed the tested weight limit specified by the manufacturer (usually measured in kilograms). This step is crucial for maintaining the package's structural integrity during transport. See the UN Marking example below:
Dangerous Goods Packaging Markings
Air shipments of hazardous materials typically necessitate compliance with UN-approved packaging, also known as Performance-Oriented Packaging (POP). Performance-oriented packaging is subjected to rigorous tests to withstand the shocks, loadings, and atmospheric pressure changes generally encountered during transportation.
Packages that have successfully met these testing requirements are marked with UN certification labels, indicating the specific level of testing they have undergone. The update also suggests referring to the Package ID Table below for assistance determining the appropriate packaging identification.
(Source: faa.gov)
Glossary | |
Density or Specific
Gravity | For single packages containing liquids, you'll find the specific gravity of a material, i.e. /Y1.5/. For packaging intended for solids or for combination packages, an "S" in uppercase will follow the gross mass, i.e., /X13/S/. |
Hydraulic Pressure | Hydraulic Pressure in Kilo-Pascal (kPa) (applies to liquids). This will follow the specific gravity. |
XX | Year of Manufacture |
USA | Country Where Package was Manufactured |
MXXX | Code for UN Certifying Agency or Manufacturer |
(Source: faa.gov)
Sample UN Markings
(Source: faa.gov)
Packaging Handling Labels for Dangerous Goods
Apart from hazard labels, proficient personnel must affix handling labels as necessary. These 14 handling labels must be employed by the staff in conjunction with the relevant hazard labels:
Label Name | Interpretation | Label |
Cargo Aircraft Only Label | For items that can only be transported via cargo aircraft, ensuring compliance with strict aviation safety regulations. | |
Limited Quantity Hazard Label for Road and Sea | Indicating that the material is suitable for transport in limited quantities on roads and by sea, emphasising responsible handling. | |
Limited Quantity Hazard Labels for Air | This signifies that limited quantities of the hazardous material can be transported via air, adhering to aviation standards. | |
Shipper / Product / Consignee | Providing vital information about the shipper, product, and consignee for clear identification and tracking. | |
Overpack Label | Required when multiple packages are bundled together in a single outer container, ensuring safe handling during transport. | |
Package Orientation Labels (Set of 2) | Guiding handlers on the proper orientation and positioning of packages to prevent damage or leakage. | |
Fragile Label | Signalling that the package contains delicate materials that require gentle handling to avoid breakage or spillage. | |
Paper Tamper Evident Seals (Label) | Indicating that tampering with the package is evident and unauthorised access can be easily identified. | |
Magnetized Material Label (100mm x 90mm) | Warning of magnetised materials that require special handling considerations. | |
Time & Temperature Sensitive Label (100mm x 100mm) | Alerting to the sensitivity of the contents to variations in time and temperature, ensuring their integrity. | |
Tip and Tell Indicator Label | Providing a visual indicator of mishandling or tilting during transport, allowing for immediate inspection. | |
Environmentally Hazardous Substance Hazard Labels (100mm x 100mm) | Signifying materials that pose an environmental hazard, demanding extra precautions. | |
Cryogenic Liquid Label (75mm x 105mm) | Identifying containers carrying cryogenic liquids which require specialised handling due to frigid temperatures. | |
Keep Away from Heat Label (74mm x 105mm) | Warning against exposure to heat sources, preventing potential reactions or damage due to elevated temperatures. |
If you encounter any issues during shipment, contact our support team at [email protected] for further information and assistance.